Assuming that you want an estimate (point and/or confidence interval) of the difference in those two probabilities, then yes, that code is reasonable (though you don't need the ILINK option when the identity link is used). If you use the default logit link then the differences from the LSMEANS statement will be differences in log odds (equivalently, log odds ratios). See the following note for more, in general, on estimating differences in probabilities: 37228 - Estimating differences in probabilities with confidence interval
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