Hi Gillett,
When you use PROC MIXED for hierarchical regression model, the parameters are estimated by using Residual Maximum Likelihood method by default. If I understood your question correctly, you are trying to use Random statement in proc mixed and the output from this model is different from individual regression model which uses OLS method for estimating the parameters. Moreover OLS method assumes errors are independent and hence there is no point in comparing the two different model outputs. For more details, you can refer SAS help & SAS documentation on PROC MIXED. I hope this would be helpful to you.
Regards,
Suresh.