Hi Jing,
I spoke with the developer of proc model and he had this response, "
For the SUR method MODEL computes a pseudo inverse of the OLS
residuals’ covariance matrix. When the OLS covariance matrix is
singular a warning is produced explaining which equations’ rows in the
covariance matrix are linearly dependent, and PROC MODEL continues with
the SUR estimation of parameters. If the user isn’t getting this warning
message for a known deficient matrix then something else is going on "
He also requested that he would be happy to look at your code and data if you wouldn't mind providing and example of the issue. - Ken