You have to specify the HOLD= option on the PARMS statement. I assume that you have specified an unstructured covariance matrix for the intercept, slope, and slope^2 and that the terms in your random model are named in that order. I also assume that conditional on the random effects, the residuals are IID (that you do not have a REPEATED statement modifying the residual variance structure).
If the above is correct, then the covariance of slope and slope^2 random effects will be the 6-th and last random effects covariance parameter in the table of covariance parameters, and that there is one parameter (residual variance) that appears in the table after the random effect covariance estimates. For covariance estimates
, , ..., , (where explicit values should be assumed for each of these terms), you could write your MIXED code as:
proc mixed data=mydata;
class subjectID ...;
model response = ...;
random intercept slope slope2 / subject=subjectID type=un;
parms () () () () () (0) () /
hold=6;
run;